REVOLUTIONISI ZA BETA ZEOLITE ZITANZWE MU BIKORWA BYINSHI-MOLECULE MU BIKORWA BIKOMEYE & CHIMICAL

Catalizike Yambere Ifungura Ubushobozi muri Alkylation no Kuzamura Bio-Amavuta

Uyu munsi, umuhanga mu guhanga udushya twa molekile ya sivile yatangaje ko azashyira ingufu mu bikorwa bya catalizike ya Beta Zeolite, ikemura ibibazo bikomeye mu gutunganya hydrocarubone iremereye ndetse n’umusaruro w’amavuta ashobora kuvugururwa. Hamwe nimiterere yihariye ya 3D 12-impeta ya pore (6.6 × 6.7 Å), Beta Zeolite ituma imikorere itigeze ibaho muguhindura molekile nini - irusha catalizator isanzwe kugera kuri 40% mubikorwa byingenzi byinganda.

Ihame rya Goldilock: Impamvu Beta Yiganje Kinini-Molecule Porogaramu
Mugihe zeolite ntoya-pore (urugero, ZSM-5) igabanya uburyo bwo kubona hamwe nibikoresho binini-pore bitanga guhitamo, ubwubatsi bwa Beta Zeolite butanga:

Uburyo bwiza bwo kwimura: Imiyoboro ya 3D ihuza imiyoboro ya molekile nini nka lubricants, bio-amavuta, na polyaromatike

Acidable Acide: Guhindura SAR (10-100 mol / mol) igenzura ubwinshi bwurubuga rwibikorwa byihariye.

Hydrothermal Stabilite: Ikomeza> 99% kristaliste kuri 650 ° C / ibidukikije

Guhindura Porogaramu
Al Intambwe ikomeye ya Alkylation
• Paraffin Alkylation: 30% hejuru ya C8 + umusaruro na acide ya aside, ikuraho ingaruka za HF / SO₂
• Synthesis ya Lubricant: Ifasha Itsinda rya III amavuta yibanze hamwe nibipimo byerekana ububobere> 130
• Dizel ishobora kuvugururwa: Catalizike C18-C22 ya alkylation ya fatty acide yo kugabanuka kwa biyogi

✅ Ubuyobozi bwa Hydrodeoxygenation (HDO)

Imikorere yo Kwunguka Yunguka Ingaruka Mubukungu
Lignin Depolymerisation 90% ikuramo ogisijeni $ 200 / toni bio-aromatics kugabanya ibiciro
Amavuta ya Pyrolysis Kuzamura 40% yumusaruro wa hydrocarubone Ufasha gutunganya uruganda
Isukari ya Biomass → Ibicanwa 5x catalizator ubuzima bwose na Al₂O₃ 30% munsi ya OPEX
Udushya twubuhanga
[Izina ryisosiyete] Guhindura ibintu byatsinze Beta gakondo:

Imyobo

Kwishyira hamwe kwa Mesopore (2-50nm) byihutisha gukwirakwizwa na 6x

Gushoboza gutunganya molekile ya 3nm (urugero, triglyceride)

Gukora Ibyuma

Ni / Mo / Beta igera kuri 98% ya HDO ikora mumashanyarazi imwe

Pt / Beta izamura alkane isomerisation guhitamo kuri 92%

Kuvugurura

100+ kuvugurura ibihe hamwe na <5% gutakaza ibikorwa

Ubushobozi bwa kokiya okiside

Inyigo Yakozwe: Umushinga Wibikoresho Byavugururwa
Umufatanyabikorwa mukuru w’ingufu z’i Burayi yagezeho:
☑️ 99.2% deoxygene yamavuta yo guteka
☑️ 18,000 barrele / kumunsi ibikorwa bikomeza
☑️ $ 35M yo kuzigama buri mwaka na hydrotreating isanzwe
* ”Cataliseri ishingiye kuri Beta yagabanije ubushyuhe bwa hydrotreating kuri 70 ° C, bituma hydrogène ikoreshwa.” * - Umuyobozi mukuru ushinzwe ikoranabuhanga